Ammonia

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    Why Your Ammonia Scrubber Is Not Working

    On paper, ammonia removal with a wet scrubber looks simple.
    Add acid. Control pH. Remove NH₃.

    In reality, many industrial scrubbers fail to remove ammonia consistently — even when all “parameters” seem correct.

    If your ammonia scrubber is not working, the problem is rarely a single variable.
    It is almost always a process issue, not a component issue.

    The Real Problem

    Ammonia absorption is not just a chemical reaction.
    It is a mass transfer process limited by:

    You don’t have “a pH”.

    Most scrubbers fail because they are designed as equipment, not as process systems.

    Why It Happens

    1. pH control is not enough

    Lowering pH shifts ammonia (NH₃) into ammonium (NH₄⁺), which is soluble.

    But:

    • local pH ≠ bulk pH
    • poor mixing creates zones where ammonia is not absorbed

    You don’t have “a single pH value”.
    You have a distribution of pH conditions inside the tower.

    2. L/G Ratio Is Too Low

    Ammonia absorption requires sufficient liquid flow.

    If the liquid-to-gas ratio (L/G) is too low:

    • contact area is reduced
    • absorption capacity is limited

    Typical failure:

    Scrubber sized on airflow only → insufficient liquid phase

    3. Poor Liquid Distribution

    Even with correct flow rate:

    • uneven spray
    • asymmetric piping
    • clogged nozzles

    create preferential paths.

    poor liquid distribution in wet scrubber nozzle spray pattern
    • Gas bypasses the liquid
    • Efficiency collapses

    This is one of the most underestimated causes of failure.

    4. Buffering Systems in the Liquid

    This is where most engineers get it wrong.

    In real systems:

    • carbonates
    • bicarbonates
    • ammonium salts

    create buffer systems

    Result:

    • pH does not drop as expected
    • acid consumption increases
    • ammonia removal becomes unstable

    The problem is not dosing.

    The problem is chemistry equilibrium.

    5. Insufficient Contact Time

    Short towers, high velocity, or undersized packing:

    • reduce residence time
    • limit absorption

    Ammonia removal is not instantaneous

    It requires time + interface

    6. Gas Conditions Are Ignored

    Temperature and saturation matter.

    • hot air reduces solubility
    • low humidity limits absorption
    • low humidity limits absorption

    A scrubber designed for “nominal conditions” will fail in real operation.

    What Most Engineers Get Wrong

    • Designing based only on airflow
    • Assuming pH = performance
    • Ignoring liquid distribution
    • Treating ammonia as a “simple pollutant”
    • Oversimplifying chemistry

    What Actually Works

    An ammonia scrubber works when:

    • L/G ratio is correctly sized
    • liquid distribution is uniform
    • pH is controlled considering buffering systems
    • contact time is sufficient
    • process variability is included in design

    This is not about adding more acid.
    It is about designing the system as a whole.

    When the System Cannot Work

    There are cases where:

    • tower is undersized
    • gas load is too high
    • variability exceeds design limits

    In these situations:

    • no adjustment will fix the problem
    • only a redesign or revamping will

    Can an Existing Scrubber Be Fixed?

    Sometimes, yes.

    Typical interventions:

    • increase liquid recirculation
    • redesign distribution system
    • introduce a second stage
    • modify chemical control strategy

    But:

    • not all systems are recoverable
    • and not all problems are “operational”

    Final Insight

    Ammonia removal is not difficult.

    But stable ammonia removal in real industrial conditions is.

    Is your ammonia scrubber underperforming?

    Contact us for a technical evaluation
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    Industrial Biotrickling Filter Odour Control System

    Biotrickling Filtration Plant

    Technical Summary

    Air flow rate: 15,000 Nm³/h
    Main pollutants:
    Reduced sulphur compounds (H₂S)
    Treatment technology: Biotrickling filtration
    Number of filtration units: 2
    Contact time: 24 seconds per filter
    Design loading: 150 Nm³/h per m³ of packing


    This case study presents an industrial biotrickling filter odour control system designed to treat emissions from a wastewater treatment plant.
    The design follows the Best Available Techniques (BAT) described in the BREF for Waste Water and Waste Gas Treatment for biological air treatment systems and VDI 3478 part 1 norm.

    Overview

    Wastewater treatment plants can generate odorous emissions associated with reduced sulphur compounds, particularly hydrogen sulfide (H₂S).

    This project involved the design and installation of an industrial odour control system based on biotrickling filtration technology to treat contaminated air streams at a wastewater treatment facility.

    The plant was designed to treat 15,000 Nm³/h of odorous air, ensuring stable removal of sulphur-based odorous compounds through biological oxidation processes.

    Engineering Solution

    The odour control system consists of two parallel biotrickling filters, each designed to treat 7,500 Nm³/h of contaminated air.

    A centrifugal fan installed upstream conveys the polluted air to the filters through a distribution manifold.

    Inside the filters, the gas stream passes through a biological packing bed, where microorganisms immobilized on the carrier oxidize hydrogen sulfide and other reduced sulphur compounds into non-odorous forms.

    Biotrickling Filter Odour Control Technology

    Each filtration unit is built around a polypropylene basin containing the biological packing and irrigation system, designed to ensure proper gas distribution and stable microbial activity.

    Main Dimensions

    Parameter

    Value

    Lenght:

    10,000 mm

    Width:

    2,500 mm

    Height:

    3,300 mm

    The filters are constructed entirely in Polypropylene (PP) to ensure resistance against corrosive gases and acidic operating conditions associated with sulphur oxidation processes.

    The packing bed is supported by a reinforced polypropylene structural grid capable of supporting loads up to 2,500 kg/m².

    Biological Packing Media

    The filtration bed is filled with open-cell volcanic lapillus, selected for its suitability in biological filtration applications.

    Packing Characteristics

    • Particle size: 14–20 mm
    • Water retention capacity: 6–10 %
    • Available water: 4–7 %
    • Neutral pH
    • High surface area for microbial colonization
    • High mechanical stability

    These characteristics promote the formation of a stable microbial biofilm capable of degrading hydrogen sulfide efficiently.

    Liquid recirculation system

    Each filter includes an independent recirculation tank and irrigation network designed to maintain optimal moisture and nutrient conditions for biological activity.

    Main equipment

    • Polypropylene recirculation tank
    • Automatic make-up water valve
    • Visual level indicator
    • Pressure level transmitter (4–20 mA)
    • Automatic purge valve
    • Two AISI 316L submersible pumps (1.1 kW) per filter
    • Nutrient dosing pump
    • Spray irrigation system covering the entire packing surface

    This configuration ensures continuous wetting of the biological packing and stable microbial growth.

    Air Handling System

    Air movement through the treatment system is ensured by a centrifugal fan equipped with inverter control, allowing flow regulation and stable operating conditions.

    Fan Specifications

    Parameter

    Value

    Nominal air flow

    15,000 Nm³/h

    Maximum pressure

    250 mm w.c.

    Motor power

    18.5 kW

    Efficiency class

    IE3

    Noise level

    < 81 dB(A)

    A standby fan rated at 20,000 Nm³/h was also included to guarantee operational redundancy and maintenance flexibility.

    Automation and Control

    The system is managed through a PLC-based control panel designed to ensure fully automatic operation.

    Control Features

    • PLC control (Siemens S7-1200 or Schneider M221)
    • HMI operator interface
    • pH monitoring
    • Conductivity monitoring
    • Automatic make-up water control
    • Inverter control for the process fan
    • Remote status signals

    This architecture ensures reliable operation and simplified plant management.

    Key Outcomes

    The installed odour control system provides:

    • Effective removal of hydrogen sulfide and reduced sulphur compounds
    • Reliable odour abatement in wastewater treatment emissions
    • Stable long-term biological operation
    • Low chemical consumption thanks to biological oxidation processes

    Biotrickling filtration technology enables continuous treatment of odorous air streams with low operating costs and high process stability.